Backport PR #19136 on branch v7.2.x (DOC: Remove unnecessary doctest-skip) - #19137

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• Do the proposed changes actually accomplish desired goals?
• Do the proposed changes follow the Astropy coding guidelines?
• Are tests added/updated as required? If so, do they follow the Astropy testing guidelines?
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• Is this a big PR that makes a "What's new?" entry worthwhile and if so, is (1) a "what's new" entry included in this PR and (2) the "whatsnew-needed" label applied?
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