> cat example.py
from starlette.applications import Starlette
from starlette.responses import PlainTextResponse
from starlette.routing import Route
from starlette.testclient import TestClient


async def value(request):
    value = request.path_params['value']
    path = request.scope['path']
    raw_path = request.scope['raw_path']
    return PlainTextResponse(
        f'value: {value}\npath: {path}\nraw_path: {raw_path}\n'
    )


app = Starlette(debug=True, routes=[
    Route('/{value:path}', value),
])


def test_app():
    client = TestClient(app)
    response = client.get('/hel%2Flo')  # /hel/lo
    result = "value: hel/lo\npath: /hel/lo\nraw_path: /hel%2Flo\n"
    assert response.text == result

> env/bin/uvicorn example:app

> curl localhost:8000/hel%2flo
value: hel/lo
path: /hel/lo
raw_path: b'/hel%2flo'

> env/bin/python -c "import example; example.test_app()"
Traceback (most recent call last):
  File "<string>", line 1, in <module>
  File "/Users/justas/work/tilaajavastuu/starlette_test/example.py", line 28, in test_app
    response = client.get('/hel%2Flo')  # /hel/lo
<...>
  File "/Users/justas/work/tilaajavastuu/starlette_test/example.py", line 14, in value
    raw_path = request.scope['raw_path']
KeyError: 'raw_path'