Papers by Benjamin Heredia
Geosciences
The significance of mineralogical maturity as a provenance indicator has long been debated and we... more The significance of mineralogical maturity as a provenance indicator has long been debated and we use this study to demonstrate that it can indeed be a powerful tool to track the distribution of sandstone reservoirs. We investigate the cause of the pronounced geographic and stratigraphic differences in mineralogical composition that are found in the Upper Triassic–Lower Jurassic Gassum Formation across the Norwegian–Danish Basin and surrounding areas. Zircon U-Pb dating of 46 sandstone samples including analysis of 4816 detrital grains are combined with quantifications of the detrital mineralogical composition and placed in a sequence stratigraphic framework. The results show that the Gassum Formation can be divided into a southeastern region with high mineralogical maturity and a less mature region to the northwest with more feldspars, rock fragments, micas, and heavy minerals. Both the mineralogical assemblage and the provenance signature have been thoroughly homogenized in the SE...
Geochimica et Cosmochimica Acta, 2022
International Journal of Earth Sciences, 2013
The Suretta nappe of eastern Switzerland contains a series of meta-igneous rocks, with the Rofna ... more The Suretta nappe of eastern Switzerland contains a series of meta-igneous rocks, with the Rofna Porphyry Complex (RPC) being the most prominent member. We present LA-ICP-MS U-Pb zircon data from 12 samples representing a broad spectrum of meta-igneous rocks within the Suretta nappe, in order to unravel the pre-Alpine magmatic history of this basement unit. Fine-grained porphyries and coarse-grained augengneisses from the RPC give crystallization ages between 284 and 271 Ma, which either represent distinct magma pulses or long-lasting magmatic activity in a complex magma chamber. There is also evidence for an earlier Variscan magmatic event at *320-310 Ma. Mylonites at the base of the Suretta nappe are probably derived from either the RPC augengneisses or another unknown Carboniferous-Permian magmatic protolith with a crystallization age between 320 and 290 Ma. Two polymetamorphic orthogneisses from the southern Suretta nappe yield crystallization ages of *490 Ma. Inherited zircon cores are mainly of late Neoproterozoic age, with minor Neo-to Paleoproterozoic sources. We interpret the Suretta nappe as mainly representing a Gondwana-derived crustal unit, which was subsequently intruded by minor Cambrian-Ordovician and major Carboniferous-Permian magmatic rocks. Finally, the Suretta nappe was thrust into its present position during the Alpine orogeny, which hardly affected the U-Pb system in zircon.
ABSTRACT The main targets for GTS next project (www.gtsnext.eu) are to develop highly refined geo... more ABSTRACT The main targets for GTS next project (www.gtsnext.eu) are to develop highly refined geological time scales, including the Upper Cretaceous. The Cretaceous period is characterised by numerous global anoxic events in the marine realm, rich ammonitic fossil assemblages and specialised foraminifera. However, lack of age diagnostic macro and micro fossils in the North Pacific sections has made it difficult to link these with global sections such as the Western Interior Basin (North America). Using advances with terrestrial C-isotope and planktic foraminifera records within Central Hokkaido we are able to correlate these sections globally. The Cretaceous Yezo group in Central Hokkaido comprises deep marine mudstones and turbidite sandstones interbedded with acidic volcanic tuffs. Using various sections within the Yezo group, we radiometrically dated tuffs at the main stage boundaries in the Upper Cretaceous. The samples derive from the Kotanbetsu, Shumarinai, Tiomiuchi and the Hakkin river sections, spanning the time from the Albian-Cenomanian up until the Campanian-Santonian boundaries, and were dated using 40Ar/39Ar, K/Ar and U-Pb techniques. Recent age constraints in the Hokkaido counterparts (Kotanbetsu sections) show good coherence between radiometric chronometers on the various Upper Cretaceous stage boundaries. These additional ages together with our isotope ages from the different sections around the Hokkaido basin are well linked by the various faunal assemblages and C-isotope curves. The combined radio isotope ages contribute to previous attempts (such as those focused in the Western Interior Basin) supporting the synchronicity of events such as global oceanic anoxic events. Finally, the ages obtained here also compliment the previous C-isotope and planktic foraminifera records allowing for a more precise climatic history of the Northwest Pacific during the Cretaceous. The research within the GTSnext project is funded by the European Community's Seventh Framework Program (FP7/2007-2013) under grant agreement no. 215458.
Bulletin of the Geological Society of Denmark, 2022
A granitic sample from the Danish island of Christiansø in the Ertholmene island group north of B... more A granitic sample from the Danish island of Christiansø in the Ertholmene island group north of Bornholm is described petrographically and geochemically, and dated using U-Pb in zircon and titanite. Zircon systematics in the sample are complicated by abundant Pb loss and a large population of zircons interpreted as being inherited. Removal of highly disturbed zircons, imprecise analyses, and assumed inherited zircons yield an upper intercept date of 1500 ± 18 Ma (MSWD = 13, n = 58). Removal of zircons with high common Pb from this population yields an identical result of 1500 ± 22 Ma (MSWD = 8, n = 34). Zircons that are ≤3% discordant give a weighted average 206Pb/238U age of 1458 ± 12 Ma (MSWD = 3.0, n = 18), and a weighted average 207Pb/206Pb age of 1495 ± 14 Ma (MSWD = 4.7, n = 19). Titanites from the sample yield a lower intercept age of 1448 ± 15 Ma (MSWD = 6.8, n = 45). The sample contains a significant number of inherited grains indicative of ages around 1.7–1.8 Ga. The relat...
Geological Magazine
Meta-sedimentary rocks recovered beneath Palaeogene basalts near the base of Ocean Drilling Progr... more Meta-sedimentary rocks recovered beneath Palaeogene basalts near the base of Ocean Drilling Program (ODP) Leg 152-917A offshore South-East Greenland were thought to be of Late Cretaceous age. This interpretation, however, has several inconsistencies as it requires a tectono-metamorphic event during the Cretaceous not recognized in the North Atlantic region, and the presence of a wide Mesozoic sedimentary basin that extended from SE-Greenland to the Rockall Plateau, for which there is currently no evidence. Here, we report a Neoproterozoic U/Pb apatite age of 905 ± 21 Ma and a younger 40Ar/39Ar isochron whole-rock age of 820 ± 40 Ma for an altered tuff layer that occurs in the upper part of the meta-volcaniclastic sequence recovered from hole 917A. The 40Ar/39Ar step-heating ages on biotite and whole-rock mini-cores from deeper in hole 917A yielded Palaeoproterozic dates that cluster around 1950 to 1850 Ma, pointing toward a Palaeoproterozoic source. The U/Pb apatite date is interpre...
An experimental procedure for precise and accurate measurements of isotope abundances by a miniat... more An experimental procedure for precise and accurate measurements of isotope abundances by a miniature laser ablation mass spectrometer for space research is described. The measurements were conducted on different untreated NIST standards and galena samples by applying pulsed UV laser radiation (266 nm, 3 ns and 20 Hz) for ablation, atomisation, and ionisation of the sample material. Mass spectra of released ions are measured by a reflectron-type time-of-flight mass analyser. A computer controlled performance optimiser was used to operate the system at maximum ion transmission and mass resolution. At optimal experimental conditions, the best relative accuracy and precision achieved for Pb isotope compositions are at the per mill level and were obtained in a range of applied laser irradiances and a defined number of accumulated spectra. A similar relative accuracy and precision was achieved in the study of Pb isotope compositions in terrestrial galena samples. The results for the galena samples are similar to those obtained with a thermal ionisation mass spectrometer (TIMS). The studies of the isotope composition of other elements yielded relative accuracy and precision at the per mill level too, with characteristic instrument parameters for each element. The relative accuracy and precision of the measurements is degrading with lower element/isotope concentration in a sample. For the elements with abundances below 100 ppm these values drop to the percent level. Depending on the isotopic abundances of Pb in minerals, 207 Pb/ 206 Pb ages with accuracy in the range of tens of millions of years can be achieved.
Canadian Journal of Fisheries and Aquatic Sciences
Accurate age data are essential for reliable fish stock assessment. Yet many stocks suffer from i... more Accurate age data are essential for reliable fish stock assessment. Yet many stocks suffer from inconsistencies in age interpretation. A new approach to obtain age makes use of the chemical composition of otoliths. This study validates the periodicity of recurrent patterns in 25Mg, 31P, 34K, 55Mn, 63Cu, 64Zn, 66Zn, 85Rb, 88Sr, 138Ba, and 208Pb in Baltic cod (Gadus morhua) otoliths from tag–recapture and known-age samples. Otolith P concentrations showed the highest consistency in seasonality over the years, with minima co-occurring with otolith winter zones in the known-age otoliths and in late winter – early spring when water temperatures are coldest in tagged cod . The timing of minima differs between stocks, occurring around February in western Baltic cod and 1 month later in eastern Baltic cod; seasonal maxima are also stock-specific, occurring in August and October, respectively. The amplitude in P is larger in faster-growing western compared with eastern Baltic cod. Seasonal p...
The main targets for GTS next project (www.gtsnext.eu) are to develop highly refined geological t... more The main targets for GTS next project (www.gtsnext.eu) are to develop highly refined geological time scales, including the Upper Cretaceous. The Cretaceous period is characterised by numerous global anoxic events in the marine realm, rich ammonitic fossil assemblages and specialised foraminifera. However, lack of age diagnostic macro and micro fossils in the North Pacific sections has made it difficult to link these with global sections such as the Western Interior Basin (North America). Using advances with terrestrial C-isotope and planktic foraminifera records within Central Hokkaido we are able to correlate these sections globally. The Cretaceous Yezo group in Central Hokkaido comprises deep marine mudstones and turbidite sandstones interbedded with acidic volcanic tuffs. Using various sections within the Yezo group, we radiometrically dated tuffs at the main stage boundaries in the Upper Cretaceous. The samples derive from the Kotanbetsu, Shumarinai, Tiomiuchi and the Hakkin riv...
ABSTRACT The Cretaceous period records evidence of sea-level changes, remarkably cyclic sedimenta... more ABSTRACT The Cretaceous period records evidence of sea-level changes, remarkably cyclic sedimentation, major perturbations in carbon cycles during anoxic events, and large scale igneous activity. Astronomically-tuned time scales are only partially consistent with recalculated Ar-Ar constraints for the Cretaceous-Paleogene (K-Pg) boundary, but differ in number and tuning of 405-kyr eccentricity related cycles. The exposures of Upper Cretaceous strata along the Red Deer River (Western Canadian Sedimentary Basin) offer a unique opportunity to examine aspects of marine, tectonic, and climatic influenced sediments. The uppermost part of the Knudsen Farm section is a well-preserved continuous section, mainly composed by climatically controlled alternations of silt and organic rich horizons, in which altered volcanic ash layers have been deposited. In this section, the K-Pg boundary has been placed at the base of a prominent coal layer (Nevis coal), approx. 24 m from the base of the c29r. We present a compilation of paleomagnetic data, chemical, colour and magnetic susceptibility proxies, and Ar-Ar, K-Ar and U-Pb (CA-TIMS) for the uppermost part of the Maastrichtian, including the base of the c29r to the K-Pg boundary and up to the lowermost Danian. High-resolution radioisotopic ages and the multi-proxy lithological and geochemical datasets are used to develop a cyclostratigraphic reconstruction of this interval, thus permitting the synchronisation of rock clocks close to the K-Pg boundary. This research is funded by the European Community's Seventh Framework Program (FP7/2007-2013) under grant agreement no [215458].
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Papers by Benjamin Heredia