P7h.15 Amines => iy ° Basic propydy :- + lewds base concept applied (L-P donor). eng Q CUg NUD > GNO ete ( bee engaged ih : Bhiline) LP 4s Rv. So, ) vedonance . So, L4 can cloak easily donation powe. * Stronger boxe. 2 In gaseous Atae, 9 5 9 Q ey N a = Cyne A . Mg Uy Ny cng NH Mg S CMe eae inoreasing ordur ap basic chatachse dup to” +I Bhect af Carbon atom . 2 In ogurous Abate , inside wat) for Higher: C- chain indudive 4739 kor mnidliye amines - - bondin h-ou a Za a - bonds Bon = on ug ge Ly pawous both inductive C+ ebfet) TR Qs welk as y-bonding RINER fovowu inductive (+t effect). Botling point are a Cig Ng Mg Ug Mg > 98 0 of Caxbon increases, Vander waal ce INCYeQue,, po, bosbing point Increases, 2 But, Our forces of aHY bike 4. bondirng | abo ab feck boiling: point. 1° 7 2° > 5° _. for isommtic amines best 4- bonding. (angi © Aniline — ; 1 g Nita tick n-N-N=O NEN & eee Sled eae — N=nC wo “ope Oo (S = Diazonium Chlovide Ss © i eo ~ oS ao s He : 2e% “ S ‘cation Schiemann — Staden cea Lite Reackon Reackn. to LD { Pend »,f ne @ on Cece On colo =N ie x = ong WH N Ghin, eS atnis vu carried %Se" oubin mild nia dudic medium. ee yelow colour — > There an known as y Dliazo ~coupling yeactians. Nig We pen Gris fue oie 6 9 N=N ven) 2 oohiat rf gy ¥ Hn - H- 5 196 : Ba on soceap > LPB [P ci wee] Na LP 44 engaged . As D and mow + Ve == = Poxa position ts blocked On onuygen is involved, ab gee on ortho only A Huomance . sVkusttavb abievnhatind dap * ) a nu Nu. R om Br, oe * en \e 2 | ZF 6 B® ae {2 SH ate bromo aniline | aul F My. Q ent Oey, 5 LP ef Nais now engaged in oysed Yeonance with 02 also. £0, a, a donation om benzene vin} wail be leas. Hence, on © ey + By® ayHaunes. — > Above wo an H-on oN j Clectrophilic. substitution hy-c- Ch Nhe Reactions. ee Brik ee oe. une NU Nit iP Nye N08 i io i cy YY NOQ (2-37.) 105, 427, 567. > AL thie ortho, Hibve pe Fed podsible-ct once. 90 Oa) @ R- é SR Spe “ce Rott ae OW Wn rs W Pate luc Bila pong wy J 1, Comin) yeack on! a wit imine, form aldehyde and gf + Gabriel Phthalamide ee c= 3 Os SPB 4 c- cc °\ Ks 0 “ou cle Phthabiid |" : iy R (one + RNA, tot th Yt Ny c-oy Shino ° ~ tim 46 to ack 1° amines only. Cavoid nixed products ) tO sor axomatic rings cannt be | uscd tee eeeReet, WY sada only once 1-2 mot Souble in atkali . RN —> mo yeaction bee 70H 10 gucouer tHe LP e- ca on O is Sy © ee a 9 = RN pa ChUaet aoe ge RO NWCA x RIN =e. VES mis is carbyramine Aut or : @_e os isoqanide est ——- RS © R-N=C Q 450) ) gol eg ee Acid, | a (v-oxide) 2 a McPBA 0 ek tae - 9 Cat A & soo grep Sonar &) R-Nua U20% 4 ide “| u iuised - — To pul Oh orygen from N-oxide “PCl, 44 util oe Pocl, & Re NU, 4 fee “eya ~ Seperation a 1° amine '- Hu + R-Chy- wu, — R=Uhy- NN pe ole i Ren ey ou ie ft (Nitroso amine’) TN ay ® Can follow SN, bez Hy Lean will be Stable ~ wed for seperation of 4° amines. eygclge tu, DN 20 aD wel - cuy-Ban nf c ares oH r ap Ceo © follss SNQ. mechantee 4 bez He caxbocation on super 1° ust be “vey Wich, ynatable ~~ Con be considered ar a method © prepare ai — 3° aminu do not sac Like tha bez H ao not © * auailable to Pucnver the LP e~ : 9 ‘ant ——= fwrtn, donation HNO. ee Tae R Beye horns Nene Oeeivoe pasrible bez (2) H> y® 4 a& & recom Get 3 fare ce 4 ce ou oT Cg Gels A Roi ar. Gi ¢ BM to Ug-b = : aK ; REN aM RN 8 oO cue e CUy--M4 ANA ieee CHG Su Q Ny-on rs m-tugyp antl fp can, Ng hou, ® be shifted oH HC ~0u sn od N- ae n — Cy c= 4 N04 (oxime) Nu-oy a -c-NW7” 3 Beckmann Rearrang mat Blan used cbs Rcati ani de from oxime > Youlomeisition 4 invowed in it fe, Auitting af H- group . ery 7M Vo ene ae eee Nyro ak > 1 wo oe q non ye nuron ye ) PS co Y-o z ‘ | 7 ¥ Homi oh Reackon + ml Lao Ruy ce é sad 2 nu ormall i 5 a eg o being 4¢! Atadble , 125 VO ; ne. puacte q ci RNU + 08, —> = —> ANE 2 S=c=S) Ras < Renae % rustordl gas —R ible, gor ahopal edy -“ ‘Aitrogen containing Compounds i e ¢ R-Cl + NaNO, —=—> R-0o-N=0 + NaCl | cohort Gubye nitride) << RoC. Ag NO. R-NoO, + Ne Agel Re es soso (nitro-alkane) a bE ; KMn04y : wu ek imemeen Cae NO 3 KMni os one CEaNOy Bicits wu oa Wy aes — Te oxidation voluich vn mundregoes depends on He Oke Group , which Ls asponsi ble for + effect. SM, being donating group. ( Gat ‘Sarge, Cu, Ba ehitess a, usse HT a hance, exttut of oxidation will sera Chumteal prapodie Op mitro- alkanes: * Reducion ep nitro—abkaned '- highest. reducin, of tere net es a age . as 05 “Caadicy” ee Spe $ ean 2nt Mal op n= Oy , Soe (Newhall)i eee torrie «ARGS Roan | egy en Teast Teauced ) he NEE oso! bic aa dua My ZO-oxy) R-N b R-NEN-R ~ooe 7c Mahest vedudng — (A29) Nay (an¥ : Chigkanacay® (Highest reduced) . ok ie. PH= 6 toF is oS Cectrolysis (Aniline ) PH= 2103 Cecholysis NUg, (Paxa- ‘amino phenct, oy os 4 a > dimi 5 in basic muduun fragmented produck obtained . | Lia, _NU Se ec, aa LiAlHY R-Nu-0u ROO’ Cpowe 1243) Kou REM NOT & R-CU,= NO + Che Page Clee a ae ee : da, ao “ eee dear R-clf- Wg ing R-CU OTN, » jut & canbon is acidic | 2 Jn Notun fusu - i ae Roe NOg ngANOGt R= CUSNOQ 1 a Rae rye Te ac no? Mi a ~N0VU Oe: © iost > Nivo alka can be duoQyvede iin, Basic _ Waedium oe quale sup. aldelydir ketones | as called as ng Caxbonyl : partial! Rydrdlyals carbouyhic acid fut Ay dolysis (2) ic) a os ou . ome ae aor eee cpa oU i of” ye Be ° Gy 7° (basic) . @ R-CU,-N ba SO Hedin © So ee ron (aldehyde) oa Selective Reduction + é &. @ Nuy), 8 Ni YN a 4 . he on idles cao 8 Etats et a (Wuy) S—> wt WS)ad HNO2 a 08” CClgNOz . (oe) —— how pican yo WP Qa (ital gas Nea! q NOz cnt UZ ~HNos \S a NOx Oy é eu es NO _, prone acid. — > used in bombs NOg | . Cyantel - ae C=n = radia cyanide ehanitile - ahi aide ee 2 rp propaitele ee oe ee pusave init @ .+ Prupasahon + Rex + KON PRO RECN 8 20 2 On C—N ee cu CaN Atay dating agence * Chunical Propertier oe " 2 i x = R-C-Ni pecn Partin Bydrdlyets -K=cr PHN Cintas R- CN conepleke ydsalge R- Bou > auidic oh wuh as bic midiwn both Ha/Pt Cire) I ON Mam Na a UAlay -C=N) Me Mae NUe OIBAL-H. 4 Wa c=N ae OM con i Ach reagunt Di-is0 b Louse enti" yo fyduide aaCdcs expecially } on. erkers &oyani 40 elude - a porn ald : if ul 0 MCPBA eNO — cn eC =N ae iz 3 morhyk Cpanade L & I CUyMgar cH CEN seoodets cng C= Hg Br NS Chg 9 “ ae fi Ong & SG) ee CHa My gts ax of He propanetin OB kekote, 27