4

Amadineu)
NO NH NH
NH

Fe
a
-HA

NC
NHOCHg
NH--Ha

fe\Het,

C0OH

CH3

NOLtHed Na
Mm4 (0H K

CHg
N
 Methylae n) 2
2
CHy-CHy NH
- NH
CHa-NH NH2 NH NH2 AWlimeNH
NaNOHA
+
NOz+HeANa 0-s'c
0-S'C
(acyiatiow) C0t CH tA
CMy NH-CH
cHa-CH AQ
Phaline
A), cHa N 2,46ma
I,3SiAmaene
N NH-c0
-CHg Dniline
NN' N'
ined HN0a
Co + -cOCHNH
a-H CH-CtHN S04,
Cone. H NaNO+HO 2
0-s'C

- ihamine
-CH
N
cHoH C0CHg NH
A Ha0(H
cH3A H,0H

Heoth
cH,-
N02
CH,ch
CHW
 daeAeMe
AmiiniM)
tAmamem Amine n)ClaehmM )
NH2
NH NH NH2 NH
Awine te
Na
NaNO,
HA + HA
NO
Na HA
NO
No 0-SC Na
diaratization No
0-sC 0-sC NOL L
0.5'C
t HA,
HÞ

Na' BDC

fucNIKCN tutNtkN HO
F4 PUzHg

CEN C=N OH NO1

CH,-NH
H-OH
 IV)
PheMeAOH Btynene)iD0- (CH,-CHg
OH

hemeh-kiemah) do
dwtZn-
0NA 2,
Aaliealaeye 4.
4-m
4091% 6

d4MAAhema
Wietote)
whe ( (CHg-CH
OH ,CHO
c.00NO OH

AAn
cOOH
 1)

NHa
NH, NHg
Asenzydhhohe
Jolusme A
(DE Na 300 t

-H
CA
hy

NO
Co0H
NH NH,
TetHe
NnQH,
KOHtAa

NH
OHTCaD Na
 cH.4-Co

4)
Bmeme H
H
H

H)S10
t gFe iwnzaokim)(FC beyatiom)(EC(FCukyatin)
A HK
-Hd -HA
enaehch
S0H
CHs
CHO
C0-CH
HAAJ Na
O
cO-C6 Hs
(O)

0No

-CH 3
H+
Co0tH
Ht

CHgtot
o
 5) 4)
9) 8)
BeAe
Ahanc 4-CN
CH,-
(CH) CHa
CHa
TAhamel khAQhGdate 2 CH- CH
CH-CHg
CHa-CH - CHa-COOH
CHa-cH,0 -CH,
NH(
OH aKid -
te -CHa
FCH 0H
id de
wARAhaad AA de amin
cO-NH2
NooH,
mdham
My50, edhanal CoONa
CGe hattintPCHC
Ha)-C-NH,
Hso C CHafco0
H, 03
CH,-CH =
CH,
CHa-CH,-0H CH- 0H CHg-
909 - Na
NH
C
NaoTA
00
=CH H
CH=0 H WHA
-CH2n NOL
Ha Pod CHa
H C
2 CHa-(ctaJa-NH2 OH+
B12 Na Ha
2CHg-
CH=0 Hg-cHi0 c
Ha -NH

2
 1)Phrtmeie R-Cp0 R-C/-NH
2 CHa-CH
2-0H
R-CH -R
cH (1)
H-CHy-- H CH4-
COOH
CHa-CH
- -CHgCHy
Na

aridh t
Na 4
to QH Na
-4ftH
NHAtet OtH
ethameisAd
4,,0 + DE
CHa-C
CHg otHa-cH,-C-oHM20H+
CHa-CH2 ’CHa-CHt
-CH,
H2
H -a -CHa
0H
CNHa
CHENa
O-N=Q)HNO2 4
-
CH tomtt
DENa
-
CHa
CHa-cH-cH-CH
H,-CiCHCH,-C
-ct,-c=NCHg
No
HO (NSK'CN
Methaal Ha-CH2C CH-CH 2
2CH-CH
CH-CHo +

+
Gg-CH,
CHa-CHÌ CH,-CH=CH-CH0 BH4Na -cH,-cHçOHaAH4
tatot tatoo-j

dil ct
’
Na Nao4 ’CHg-CH-CH,-CH =0
0H CtHa
,cHa CH tH
-CH
-CH,
-ch-cHO GH-CHCHO -CH-CHH-CH =0 -CH-
CHa
-H,0
-CH
cH =
-CHO
=CHCH, kinmomaledehyde
hajaa)
Phey 3 H
0 =0
TH=CH-CHO 6HyNa
|Cowe
SIaH, CH-CH Hso4
-H0
H2S04

0
 2-CH C}
- 2CHy-

H
C

DE
i. KCN W)

Naot t. Na to
OH,
CH,-CH AremeaAd
)0=C=0
O14

-cH=0
-CH, H-CH,-CHEO H
CH=0
cH-CHg
-He0
S13K

tt

tae
2CHy-
 ChAetlhaMeV)

CHa-CH2 CH,-C-U
H; CH,-C
CH, CH,-CH,-c
hlethane
CH¡-CH, ta
-
H,- CH,
OH d - -
CH A
- CN
K*
Rd K*CN
H twSR)CH,
CH,-cEN -KU
-KU
tNSR(H4-c-CEN H, K*CN
CH,-CH,-CEN
’
’CHaCH,-C N
UH
e
CHa-CH,
-CSN
N HNO 2

g-CH2-c=
=0) N
CN
CHa CH,
H,-cH;-C C (tehemhid'
H0
tH A[H}
NCtlg
-H, CH -CH, -
CtH,-C=O
CH- -C C
H,
H, -CH
-c -CH,
=0 (HO=0)HNO2
-N
CHg
NH, -0H
CHa-CO
(me!

(aleeho)
O=C= O

CHa-CH- GH4-OH
CH¡- OM)
-H2

CH3-CH CHy-CH-CH
CHa-C Ha ü) H,0Ht

S13K
-Ha

2
OH

cHs-c-CHg ’CH C-CH3CHg- CH =CH,

4) Aezaloehycde e aetahemse
CH
tu
S73

2Bayzaldcdyde CH-CHs C-co H

’
S73K

’ CHn-C- CH,
) H0 |H
CHa
 KMM O4 IH
’CHa -C00H + i

#cH2

-c00H)
KmwosH, 2c H a
cH-CHa
cHaBo0o
’CHac00H
/0H*
K MM O 4

to ethameC a
10) BankaMe-2gl
C C H 2 - cHa
cH,-
OH

2|CHa- Co0H

ct
6 HO0 C-(CHz-co0H

12) aeme

CH-CH3
Km0 |0H

¿-cH3

1s)ene
AtanzaldslaydCHO
 KMO4 10Ht

V) h0le|CS

1X) 2 A 4 s OH

XI) No h,0 t H,s04

CHa -CH-CH =0

CH=O

hostttts Co), 0 ’ctta-c-CHa

cH)-cHg

4) Bakam-2-Al
CHa-H-cH,- cH

s) B u t a m - - e
-cH,- COOH
Ha-CH,-CHa-0f) KMmo4 10H ’ CH- CH,
CHa-C

coOH
CHa- OH KMyO4 TOH
 cH, H)
443K
-H20

Mydoatom
cHa -CH -CHg

cHa -CHa-CHa 4 43 K

-Ha0
s0tyH CH=H
;dahydhakian)

CH- CH2-CH0H

KOttt,

ttt Nai
CHa-H=CH,
CHgC2-CH

+H A
CH 4-CH = CH,
Redutinag agt
H|Pt

U)D16AL- H
|HA
N) H2N -NH, lOH

x) felHA
mHA

Ha lPod CHa-CH -cH,- 0H

CHa-cH, -cH =Q

CHa C-CH3 ’CH -CH -cHa

2 HJ

CH= 0 CH2-H
H4 tPt

2(H)

4 (H) Ha tc Ha-0H
-2Ha0

Co0H
4(H]
- 2 He0
 -CHa
CHa-CH
-CHo-OH CHa-CH=CH
CH-CHAh.
Prhog +HA
CH-cHa-
CHe
)J(henie
CHa
-CH=CHa
CHa-
CH-CHa CH2
Hg
- OH LoHn3
-CH
CHa
Hg
ydsalia B20,
H1
4 H,
+HA )
H=CH, 2
CH2
CH-CH= H2-CH CH
-CH
-CH=CHa
CHg C
Ho-CH=CHa
CHg-C
-C
CH CH
 rthanawe twwy
CHo-Ct2-NH,
RAhaMimithie ta
6) CHa-N 4 (HJ

NH,
Ai AA H4 ’ctla- ctg -
-HO
CHa -c - NH

CHo-C=N
(ateihenhed")
Aenazaldcayce
CHO
DIGAL-H

Fel He ’ CtHa-CHy- NH,

CHcH,- NO

CHO

PdeaSO41s

CH-CH,- CH=0

14)
Phaagan NH-N Ha0H"
9CHa-CH-cHa
CH-0 NtHe-NHL) 0H°gyeel

16) Acedanhinane Àa etaytmLAAL

2-cH NHa- NH] 0Hgyeel CHe-cH3