632

Apéndice B
Tabla B.l Datos selectos de propiedades físicas''

Peso GE A //m(7m)ÍV A/7v(/'b)‘V (A H f f j (A HCY>

Com puesto Fórmula molecular (20°/4°) Tm(°C)h kJ/mol Tb(°CY‘ kJ/mol T ,( K) f P c(atm>'/ kJ/mol kJ/mol

Acetaldchído CH 3CHO 44.05 0.78318° -123.7 — 20.2 25.1 461.0 - - I 66.2(g) - 1 192.4(g)
Acetato de etilo c 4h xo 2 88.10 0.901 -83.8 — 77.0 — 523.1 37.8 -463.2(1) -2246.4(1)
-4 2 6 .8(g)
A cetato de metilo c 3h 6o 2 74.08 0.933 -98.9 - 57.1 - 506.7 46.30 -409.4(1) -1595(1)
Acetileno c 2h 2 26.04 - - - -81.5 17.6 309.5 61.6 +226.75(g) —1299.6(g)
Acetona C -M .0 58.08 0.791 -95.0 5.69 56.0 30.2 508.0 47.0 -248.2(1) -1785.7(1)
-2 l6 .7 (g ) —1821 -4(g)
Ácido acético CH3COOH 60.05 1.049 16.6 12.09 118.2 24.39 594.8 57.1 -486.18(1) -871.69(1)
—438.15(g) -919.73(g)
Ácido benzoico c 7h 6o 2 122.12 1.2661S° 122.2 - 249.8 - — - - -3226 .7(g)
Ácido fórmico CH 20 2 46.03 1.220 8.30 12.68 100.5 22.25 — - -409.2(1) -262.8(1)
-3 6 2 .6(g) -
Ácido fosfórico H3P04 98.00 1.83418° 42.3 10.54 (—i H20 a 213°C) - - -1 2 8 1 .l(c) -
-I27 8 .6 (ac),
1H, 0
Ácido nítrico HNO3 63.02 1.502 -4 1.6 10.47 86 30.30 -173.23(1)
-206 .57(ac)
Ácido oxálico c 2h 2o 4 90.04 1.90 Se descom pone a 186°C -826.8(c) -2 5 1 .9(s)
Ácido sulfúrico h 2s o 4 98.08 1.83418° 10.35 9.87 Se descompone a 340°C - - -811.32(1) —
-907.5 l(ac)
Agua h 2o 18.016 1,004° 0.00 6.0095 100.00 40.656 647.4 218.3 -285.84(1)
—241,83(g) :
Alcohol bencílico c 7h xo 108.13 1.045 -15 .4 205.2 -3741.8(1)
Alcohol etílico c 2h , o h 46.07 0.789 -114.6 5.021 78.5 38.58 516.3 63.0 -277.63(1) -1366.91(1)
(ctanol) -235.3 l(g) —1409.25(g)
Alcohol C3H5OH 60.09 0.785 -89 .7 82.24 508.8 53.0 -310.9(1) -1986.6(1)
isopropílico
Alcohol m etílico CH 3OH 32.04 0.792 -9 7.9 3.167 64.7 35.27 513.20 78.50 -238.6(1) 726.6(1)
(metanol) - 20 1.2(g) -764.0(g)
Alcohol C3H5OH 60.09 0.804 -127 97.04 536.7 49.95 -300.70(1) -2010.4(1)
H-propilico -2 5 5 .2(g) —2068.6(g)
Am oniaco 17.03 -77.8 5.653 -33.43 23.351 405.5 111.3 -67.20(1)
—4 6.19(g) -38 2.5 8(g)
Anilina C6H7N 93.12 1.022 -6.3 - 184.2 - 699 52.4 '- -

Azufre S j¡ 256.53 1.96 119 14.17 444.6 83.7 - - +0.30(c) -

(m onoclínico)
Azufre Ss 256.53 2.07 113 10.04 444.6 83.7 - - 0(c) -
(rómbico)
Benceno C6H« 78.11 0.879 5.53 9.837 80.10 30.765 562.6 48.6 +48.66(1) -3267.6(1)
+82.93(g) —3301 -5(g)
Benzaldehido c 6h 5c h o 106.12 1.046 -26 .0 - 179.0 38.40 - - -88.83(1) -3520.0(1)
—40.04(g) -
Bicarbonato de N aHC Oj 84.01 2.20 >e descom pone a 270°C — - -9 45.6(c) -
sodio
Bisulfato de N aH S 04 120.07 2.742 - - - - - - - 1 126.3(c) -
sodio
Bromo Br2 159.83 3.119 -7 .4 10.8 58.6 31.0 584 102 0(1) _
Bromuro de etilo C2H5Br 108.98 1.460 -119.1 - 38.2 - 504 61.5 -54 .4(g) -
Bromuro de HBr 80.92 - -8 6 - -6 7 - - - -36.23Cg) -
hidrógeno
1.2-butadieno c 4h 6 54.09 _ -136.5 — 10.1 _ 446 _ _ _
1.3-butadieno c 4h 6 54.09 - -109.1 - -4 .6 - 425 42.7 - -
«-butano C4H i0 58.12 - -138.3 4.661 - 0.6 22.305 425.17 37.47 -147.0(1) -2855.6(1)
-1 2 4 .7(g) -28 7 8 .5(g)
1-Buteno c 4h 8 56.10 _ -185.3 3.8480 -6.25 21.916 419.6 39.7 + I.17(g) —2718.6(g)
Carbonato de C aC 0 3 100.09 2.93 Se descompone a 825°C —1206.9(c) -
calcio
Carbonato de Na2C 0 3 105.99 2.533 Se descom pone a 854°C - - - 1 130.9(c) -
sodio

Tablas de propiedades físicas

Carbono C 12.010 2.26 3600 46.0 4200 - - - 0(c) -39 3.5 l(c)
(grafito)
Carburo de CaC2 64.10 2.22 l8° 2300 - - - - - -62.76(c) -
calcio
Cianuro de HCN 27.03 _ -1 4 - 26 — - - + 130.54(g) -
hidrógeno

(continúa)

633
 634
Apéndice B
T a b la B .l (C o n tin ua c ión .)

Pe so GE A í l m(TmY- ( A // C)V
Tm(°C)h

O
C o m p u e s to F ó rm u la m o le c u la r (20 74 °) k J/m o l k J/m o l 7l-(K) / k J/m o l k J/m o l

£
C ia n u ro d e so d io N aC N 49.01 5 62 16.7 1497 155 - -8 9 .7 9 (c ) —

C ic lo h c x a n o C6H,2 8 4 .1 6 0 .7 7 9 6.7 2 .6 7 7 8 0 .7 30.1 5 5 3 .7 4 0 .4 -1 5 6 .2 (1 ) -3 9 1 9 .9 (1 )

123.1(1) -3 9 5 3 .0 ( g )
C ic lo p e n ta n o C5H,ü 7 0 .1 3 0 .7 4 5 -9 3 .4 0 .6 0 9 4 9 .3 2 7 .3 0 5 1 1 .8 4 4 .5 5 -1 0 5 .9 (1 ) -3 2 9 0 .9 (1 )
- 7 7 .2 ( g ) —3 3 1 9 .5 (g )
C in c Zn 6 5 .3 8 7 .1 4 0 4 1 9 .5 6 .6 7 4 9 07 11 4.7 7 0 (c )
C lo ro C l2 70.91 - 1 0 1 .0 0 6 .4 0 6 - 3 4 .0 6 2 0 .4 4 1 7 .0 76.1 0 (g )
C l o ro b e n c e n o C 6i l 5CI 112 .5 6 1.107 ^ 5 13 2.1 0 3 6 .5 6 3 2 .4 4 4 .6
C lo r o e t a n o c 2 h 5c i V er c lo ru r o d e e tilo
C lo ro fo rm o CHC1., 119 .3 9 1.489 -6 3 .7 - 6 1 .0 5 3 6 .0 5 4 .0 -1 3 1 .8 (1 ) -3 7 3 (1 )
C lo ru r o d e c alc io C a C l2 110 .9 9 2 .1 5 2 i5° 78 2 2 8 .3 7 >1600 - 7 9 4 .9 6 ( c )
C lo ru r o d e e tilo C 2 H ,C1 6 4 .5 2 0 .9 0 3 15° -1 3 8 .3 4 .4 5 2 13.1 2 4 .7 4 6 0 .4 5 2 .0 - 1 0 5 .0 ( g )
C lo ru ro d e HC1 3 6 .4 7 - 1 1 4 .2 1.99 -8 5 .0 16.1 3 2 4 .6 81.5 - 9 2 .3 l( g )
h id ró g e n o
C lo ru ro d e M g C l2 9 5 .2 3 2.3 2 5 25° 71 4 43.1 1418 136.8 - 6 4 1 .8(c )
m a g n e sio
C lo ru ro d e C H 3CI 5 0 .4 9 - - 9 7 .9 - -2 4 416 .1 6 5 .8 0 - 8 1 .9 2 (g )
m e tilo
C lo ru ro d e so d io N aC l 5 8 .4 5 2 .1 6 3 80 8 2 8 .5 1465 170.7 - 4 1 1.0(c)
C o b re Cu 6 3 .5 4 8 .92 1083 13.01 2 5 95 3 0 4 .6 0 (c )
« -D e c a n o C k )H 22 1 42.28 0 .7 3 0 - 2 9 .9 - 173.8 6 1 9 .0 20.8 -2 4 9 .7 (1 ) -6 7 7 8 .3 (1 )
- 6 8 2 9 .7 ( g )
D ió x id o d e so2 6 4 .0 7 - 7 5 .4 8 7 .4 0 2 10.02 2 4.9 1 4 3 0 .7 -2 9 6 .9 0 (g )
a z u fre
D ió x id o d e co2 44 .01 - 5 6 .6 8 .33 (S e su b lim a a 3 0 4 .2 7 2.9 -4 1 2 .9 (1 )
c a rb o n o a 5 .2 a tm - 3 9 3 . 5 (g )
D ió x id o d e n o 2 46 .01 - -9 .3 7 .3 3 5 2 1 .3 14.73 4 3 1 .0 1 0 0 .0
n itró g e n o
D ió x id o de sío 2 6 0 .0 9 2 .2 5 1710 14.2 2230 -8 5 I.0 ( e )
silic io
D isu lfu ro d e cs2 7 6 .1 4 1 .26 122°/2l,<' - 112.1 4 .3 9 4 6 .2 5 2 6 .8 5 5 2 .0 7 8 .0 1-87.9(1) -1 0 7 5 .2 (1 )
c a rb o n o + 1 1 5.3(g ) 1 1 0 2 .6 (g )
E tan o C 2H 6 3 0.0 7 - - 1 8 3 .3 2 .8 5 9 - 8 8 .6 14.72 3 0 5 .4 4 8 .2 -8 4 .6 7 (g ) - 1 5 5 9 .9 ( g )
É te r d ie tíiic o (C 2 H 5)20 7 4.1 2 0 .7 0 8 2S° - 1 1 6 .3 7 .30 3 4 .6 2 6 .0 5 467 3 5 .6 -2 7 2 .8 (1 ) -2 7 2 6 .7 (1 )
3 -E til h e x a n o C « H ,k 1 14.22 0 .7 1 7 - — 118.5 3 4 .2 7 5 6 7 .0 2 6 .4 -2 5 0 .5 (1 ) -5 4 0 7 .1 (1 )
- 2 1 0 .9 ( g ) - 5 5 0 9 . 8 (g)
E tilb e n c e n o C XH 10 106 .16 0 .8 6 7 -9 4 .6 7 9 .1 6 3 136.2 3 5 .9 8 6 1 9 .7 3 7 .0 -1 2 .4 6 (1 ) -4 5 6 4 .9 (1 )
+ 2 9 .7 9 (g ) - 4 6 0 7 . l( g )
E tilc n g lic o l C 2H 60 2 6 2 .0 7 1 .1 1 3l9° -1 3 11.23 197.2 5 6 .9 — -4 5 1 .5 (1 ) -1 1 7 9 .5 (1 )
- 3 8 7 . 1(g)
E tile n o C 2 H4 2 8 .0 5 - 1 6 9 .2 3 .3 5 0 - 1 0 3 .7 13.54 283.1 5 0.5 + 5 2 .2 8 (g ) - 1 4 l0 .9 9 (g )
Fenol C ftH jO H 94.11 1 .0 7 125’ 4 2 .5 11.43 1 81.4 — 692.1 6 0 .5 -1 5 8 .1 (1 ) - 3 0 6 3 . 5 (s)
- 9 0 .8 ( g )
F lu o r u ro d e HF 2 0 .0 _ -8 3 20 5 0 3 .2 - 2 6 8 . 6 (g )
h id ró g e n o - 3 1 6 .9 (a c , -
200)
F o rm a ld e h íd o H 2C O 3 0 .0 3 0 .8 1 5 -20° -9 2 - -1 9 .3 2 4 .4 8 - - - 1 1 5.90 (g) - 5 6 3 .4 6 ( g )
F o sfa to d e c a lc io C a 3( P 0 4 )2 3 1 0 .1 9 3 .1 4 1670 - - - - —4 1 3 8 (c ) -
F ó s fo ro (b la n c o ) P4 1 23.90 1.82 4 4 .2 2.51 280 49.71 - - -
F ó s fo ro (ro jo ) P4 1 23.90 2 .2 0 5 9 0 43a,m 8 1 .1 7 S e e n c ie n d e c o n e l a ire , a 7 2 5 °C — - 1 7 .6 ( c ) -
0 (c )
G lic e ro l C jH g O j 9 2 .0 9 I .2 6 0 50” 18 .20 18.30 2 9 0 .0 - - -6 6 5 .9 (1 ) -1 6 6 1 .1 (1 )
H e lio He 4 .0 0 - - 2 6 9 .7 0 .0 2 - 2 6 8 .9 0 .0 8 4 5 .2 6 2 .2 6 0 (g ) -
w -H e ptano C 7 H I6 1 0 0 .2 0 0 .6 8 4 -9 0 .5 9 14.03 9 8 .4 3 3 1 .6 9 5 4 0 .2 2 7 .0 -2 2 4 .4 (1 ) -4 8 1 6 .9 (1 )
- 1 8 7 . 8 (g) - 4 8 5 3 . 5 (g )
« -H e x a n o c 6 h ,4 8 6 .1 7 0 .6 5 9 -9 5 .3 2 13.03 6 8 .7 4 2 8 .8 5 5 0 7 .9 2 9 .9 -1 9 8 .8 (1 ) -4 1 6 3 .1 (1 )
- 1 6 7 . 2 (g ) - 4 1 9 4 .8 (g )
H id ró g e n o h2 2 .0 1 6 _ - 2 5 9 .1 9 0 .1 2 - 2 5 2 .7 6 0 .9 0 4 33 .3 12.8 0 (g) -2 8 5 .8 4 ( g )
H ie rro Fe 5 5 .85 7 .7 1535 15.1 2800 3 5 4 .0 - - 0 (c )
H id ró x id o d e N H 4O H 3 5 .0 3 - - -3 6 6 .4 8 ( a c )
a m o n io

Tablas de propiedades físicas

H id ró x id o d e C a (O H ) , 7 4 .1 0 2 .24 ( - H 20 A 5 8 0 °C ) - 9 8 6 .5 9 ( c ) -
c a lc io
H id ró x id o d e M g (O H )2 5 8 .43 2 .4 d e s c o m p o n e a 3 5 0 °C
m a g n e s io
H id ró x id o d e N aO H 4 0 .0 0 2 .1 3 0 319 8 .34 1390 - - - - 4 2 6 .6 (c ) -
so d io - 4 6 9 .4 (a c )

(continua)

635
 636
Apéndice B
T ab la B .l (C o ntinu ac ió n.)

P eso GE A/Vm(7-mF A /7v(7-b)‘V (A ( A // C)'V

C o m p u e s to F ó rm u la m o le c u la r (2 0 °/4 ° ) Tm(°C)h k J/m o l 7'b(° C )'/ k J/m o l TC(K V k J/m o l k J/m o l

Iso b u ta n o C 4H | 0 5 8 .1 2 - -1 5 9 .6 4 .5 4 0 -1 1 .7 3 2 1 .2 9 2 40 8.1 3 6.0 -1 5 8 .4 (1 ) -2 8 4 9 .0 (1 )

- 1 3 4 . 5 (g ) —2 8 6 8 .8 (g )
Iso p e n ta n o C 5 H ,2 7 2 .1 5 0 .6 2 19° -1 6 0 .1 2 7 .7 4 6 1 .0 0 3 2.9 -1 7 9 .3 (1 ) —3 507 .5(1 )
_ - 1 5 2 .0 ( g ) —3 5 2 9 .2 (g )
M a g n e sio Mg 2 4 .3 2 1.74 650 9 .2 1120 131.8 - 0 (c ) -
M e rc u rio Hg 20 0.61 13.54 6 -3 8 .8 7 - 3 5 6 .9 0 (c )
M e ta n o ch 4 16.04 -1 8 2 .5 0 .9 4 - 1 6 1 .5 8 .1 7 9 19 0.7 0 4 5 .8 - 7 4 .8 5 ( g ) - 8 9 0 .3 6 (g )
M e til a m in a c h 5n 3 1 .0 6 0 .6 9 9 “ “ ° -9 2 .7 - -6 .9 - 4 2 9 .9 7 3 .6 0 - 2 8 .0 ( g ) -1 0 7 1 .5 (1 )
M e til e til c e to n a C 4 H xO 7 2 .1 0 0 .8 0 5 -8 7 .1 - 7 8.2 3 2 .0 - - -2 4 3 6 (1 )
M o n ó x id o d e CO 28.01 - -2 0 5 .1 0 .8 3 7 -1 9 1 .5 6 .0 4 2 133 .0 34 .5 - 1 1 0.5 2(g) - 2 8 2 .9 9 ( g )
c a rb o n o
N a fta le n o C ioH g 1 28 .1 6 1.145 8 0 .0 2 1 7 .8 - - - —5 15 7(g )
N íq u e l Ni 5 8 .6 9 8 .9 0 1452 2900 0 (c )
N itra to de N H 4N O , 8 0 .0 5 1 .72 52S° 169.6 5 .4 se d e sc o m p o n e a 2 1 0 °C —3 6 5 .1 4 (c ) —
a m o n io -3 9 9 .3 6 ( a c )
N itra to d e so d io N aN 03 8 5 .0 0 2 .2 5 7 310 15.9 Se d e sc o m p o n e a 3 8 0 °C - - 4 6 6 . 7(c ) —
N itrito d e so d io N aN O j 6 9 .0 0 2 .1 68 °° 271 Se d e sc o m p o n e a 3 2 0 °C - -3 5 9 .4 ( c ) -
N itro b e n c e n o C ftH sO iN 123.11 1.203 5.5 - 2 1 0 .7 - - - - -3 0 9 2 .8 (1 )
N itró g e n o n 2 2 8 .0 2 - - 2 1 0 .0 0 .7 2 0 -1 9 5 .8 5 .5 7 7 12 6 .20 3 3.5 0 (g) -
« -N o n a n o c <,h 2o 128 .2 5 0 .7 1 8 -5 3 .8 — 15 0.6 — 5 95 2 3 .0 -2 2 9 .0 (1 ) -6 1 2 4 .5 (1 )
—6171 -0 (g )
« -O c ta n o C 8 H ib 11 4.2 2 0 .7 0 3 - 5 7 .0 — 125.5 — 5 6 8 .8 2 4.5 -2 4 9 .9 (1 ) —54 70.7 (1)
- 2 0 8 .4 ( g ) —5 5 1 2 .2 (g )
O x id o d e c a lc io C aO 5 6 .0 8 3 .3 2 2570 50 2850 - - - - 6 3 5 . 6 (c ) —
Ó x id o de M gO 4 0 .3 2 3 .6 5 2900 7 7 .4 3600 - - - - 6 0 1 .8 (c ) —
m a g n e sio
Ó x id o d e p lo m o Pb O 22 3.2 1 9.5 886 11.7 1472 213 - 2 1 9 .2 (c ) —
Ó x id o fé rric o F c iO j 159 .7 0 5 .12 Se d e sc o m p o n e a 15 6 0 °C - 8 2 2 . 2(c )
Ó x id o fe rro so FeO 7 1.85 5.7 - 2 .6 6 . 5 ( c )
Ó x id o n ítric o NO 30.01 -1 6 3 .6 2.301 -1 5 1 .8 13.78 1 79 .20 6 5.0 + 9 0 .3 7 (g )
Ó x id o n itro so N 20 4 4 .0 2 1 .2 2 6 '89° -9 1 .1 3 0 9 .5 7 1 .7 0 + 8 1 .5 (g )
O x íg e n o o2 3 2 .0 0 - 2 1 8 .7 5 0 .4 4 4 -1 8 2 .9 7 6 .8 2 15 4.4 4 9 .7 0 (g)
/i-P e n ta n o C 5 H I2 7 2 .15 0 . 6 3 18° -1 2 9 .6 8 .3 9 3 3 6 .0 7 2 5 .7 7 4 6 9 .8 0 33.3 -1 7 3 .0 (1 ) -3 5 0 9 .5 (1 )
- 1 4 6 .4 ( g ) - 3 5 3 6 . l( g )
1-P e n te n o c 5h I(, 70 .1 3 0.641 -1 6 5 .2 4 .9 4 2 9 .9 7 474 3 9 .9 -2 0 .9 ( g ) - 3 3 7 5 . 8 (g)
P e n tó x id o d e p 2o 5 141 .9 5 2 .3 8 7 S e su b lim a a 2 5 0 °C - - - 1 5 0 6 .2 ( c ) -
fó sfo ro
P e n tó x id o d e n 2o 5 108 .2 0 1.6 3'*° 30 - 47 - - - -
n itró g e n o
P lo m o Pb 20 7.2 1 1 1.33 7 20720'' 3 2 7 .4 5 .1 0 1750 179.9 - 0 (c) -
P ro p a n o C 3H x 4 4 .0 9 - -1 8 7 . 6 9 3 .5 2 -42.07 18.77 3 6 9 .9 4 2 .0 -1 1 9 .8 (1 ) -2 2 0 4 .0 (1 )
- 1 0 3 . 8 (g) - 2 2 2 0 . 0 (g )
//-P ro p il-b e n c e n o c 9h ,2 12 0.1 9 0 .8 6 2 - 9 9 .5 0 8 .54 159.2 3 8 .2 4 6 3 8 .7 31.3 -3 8 .4 0 (1 ) -5 2 1 8 .2 (1 )
+ 7 .8 2 (g ) - 5 2 6 4 .4 8 ( g )
P ro p ile n o c 3h 6 4 2 .0 8 - - 1 8 5 .2 3 .0 0 - 4 7 .7 0 18.42 365.1 4 5 .4 + 2 0 .4 l( g ) -2 0 5 8 .4 ( g )
S ilic a to d e c a lc io CaSiO-* 11 6.1 7 2 .9 1 5 1530 4 8 .6 2 - - - -I5 8 4 (c ) -
S u lfa to c ú p ric o C U SO 4 159.61 3 . 6 0 6 150 S e d e sc o m p o n e a > 6 0 0 °C - 7 6 9 .9 ( c ) -
- 8 4 3 .1 (a c )
S u lfa to d e (N H 4 ) 2 S 0 4 13 2.1 4 1.769 513 - S e d e sc o m p o n e a 5 1 3 °C - 1 1 79 .3(c)
a m o n io tra s la fu sió n - 1 1 7 3 .1 (ac )
S u lfa to d e c a lc io C aS04 136.15 2 .9 6 - - - - - - - 1 4 3 2 . 7 (c ) -
- 1 4 5 0 .4 (a c )
S u lfa to d e C a S 0 4 -2 H 20 172.18 2 .3 2 ( -1 .5 H 20 a 12 8 ° C ) - - - - 2 0 2 l( c ) —
c a lc io (y e so )
S u lfa to d e so d io N aS04 142.05 2 .6 9 8 8 90 2 4.3 - - - - - 1 3 8 4 . 5(c ) -
S u lfito d e so d io N a 2S 0 3 126.05 2 . 6 3 3 150 S e d e sc o m p o n e - - - 1 0 9 0 .3 ( c ) -
S u lfu ro de H 2S 3 4.0 8 - - 8 5 .5 2 .3 8 - 6 0 .3 18.67 3 7 3 .6 88 .9 -1 9 .9 6 (g ) -5 6 2 .5 9 (g )
h id ró g e n o
S u lfu ro d e so d io N a 2S 7 8 .05 1.856 950 6 .7 - - - - - 3 7 3 . 2 (c ) -
S u lfu ro fe rro so FeS 8 7.9 2 4 .8 4 1193 - - - - - —9 5 . l(c ) -

Tablas de propiedades físicas

T etra c lo ru ro d e C CI4 153 .8 4 1.595 - 2 2 .9 2.51 7 6 .7 3 0 .0 5 5 6 .4 4 5 .0 -1 3 9 .5 (1 ) -3 5 2 .2 (1 )
c a rb o n o - 1 0 6 .7 ( g ) - 3 8 5 .0 ( g )

T e tró x id o de n 2o 4 9 2 .0 1.448 - 9 .5 — 21 .1 — 4 3 1 .0 9 9 .0 + 9 .3 (g ) _
n itró g e n o
T io su lfa to de N a 2 S 20 3 158.11 1.667 - - - - - - - 1 1 1 7 . l(c ) -
so d io

(continúa )

637
T a b la B .l (C on tinu ac ió n.)

Peso GE A / / n, ( r m)<v A Hv(Thr J (A H f f J (A H J J

C o m p u e s to F ó rm u la m o le c u la r (20 74 °) Tm(°C)h k J/m o l nrer1 k J/m o l W ' /Jc(atm>(' k J/m o l k J/m o l

T olu e n o C 7H 8 9 2.1 3 0 .8 6 6 - 9 4 .9 9 6 .6 1 9 11 0.6 2 3 3 .4 7 5 9 3 .9 4 0 .3 + 12.00(1) -3 9 0 9 .9 ( 1 )

+ 5 0 .0 0 (g ) - 3 9 4 7 .9 ( g )
T rió x id o de S03 8 0 .0 7 - 16.84 2 5 .4 8 4 3 .3 4 1 .8 0 4 9 1 .4 83 .8 - 3 9 5 . 18(g) —
a z u fre
w -X ile n o C SH , 0 10 6.1 6 0 .8 6 4 - 4 7 .8 7 11.569 139 .1 0 3 6.4 0 61 9 3 4 .6 -2 5 .4 2 (1 ) -4 5 5 1 .9 (1 )
+ 1 7.24 (g ) —4 5 9 4 .5 (g )
o -X ile n o c 8h , () 10 6.1 6 0 .8 8 0 - 2 5 .1 8 13 .598 144.42 3 6.82 6 31 .5 3 5 .7 -2 4 .4 4 (1 ) —45 52.9 (1)
+ 1 8 .9 9 (g ) -4 5 9 6 .3 ( g )
/;-X ile n o c 8h , () 10 6.1 6 0.861 13.26 17.11 138.35 3 6.0 7 61 8 3 3.9 -2 4 .4 3 (1 ) -4 5 5 2 .9 1 (1 )
1 7.9 5(g) - 4 5 9 5 . 2 (g )
Y odo I2 2 5 3 .8 4 .9 3 113.3 - 184.2 - 8 2 6 .0 - 0 (c ) -

“ A d a p ta d o e n p a rte d e D. M . H im m e lb la u . Basic Principies and Calculations in Chemical Engineering. 3a. e d ic ió n . © 1974. ta b la s D. 1 y F. I A d a p t a d o c o n a u to r i-

z a c ió n d e P re n tic e -H a ll. Inc ., E n g le w o o d C lifís. NJ.
h P u n to d e fu sió n a 1 a tm .
c C a lo r d e fu sió n a Tm y 1 a tm .
d P u n to d e e b u llic ió n a 1 a tm .
e C a lo r d e v a p o riz a c ió n a y 1 a tm .
1 T e m p e ra tu ra c rític a .
8 P re sió n c rític a .
h C a lo r d e fo r m a c ió n a 2 5 ° C y 1 atm .
' C a lo r d e c o m b u stió n a 2 5 °C y I a tm . L o s e sta d o s e stá n d a r d e los p ro d u c to s so n C O if g ) , H 20 ( I ) , SC>2(g ), H C l(a c ) y N 2(g ). P ara c a lc u la r A/V°c c o n H iO (g ) c o m o
p ro d u c to , su m e 4 4 . 0 1nw al v a lo r ta b u la d o , d o n d e nw = m o le s d e H 2O fo rm a d o s/m o l e s d e c o m b u s tib le q u e m a d o s.
i P ara tr a n s fo rm a r A H a k c a l/m o l, d iv id a el v a lo r d a d o e n te 4 .1 8 4 ; p a ra c o n v e rtir a B tu /lb /m o l, m u ltip liq u e p o r 4 3 0 .2 8 .
T a b la B .2 C a p a c id a d e s c a lo rífic a s"

F o rm a I: C y,[kJ/m ol-°C )] o [k J/(m o l-K )] = a + bT + c T 2 + dT*

F o rm a 2 : C/,[k J/m o l-° C )] o [k J/(m o l-K )] = a -t- b T + c T ~ 2

Ejemplo: (Cp)acctonMs) = 0 .0 7 1 9 6 + (2 0 .1 0 X 10 5) T - (1 2 .7 8 X I 0 “ x) 7 '2 + (3 4 .7 6 X l O " 12) / -3, d o n d e 7 'c s t á e n ° C .

Nota: L as fó rm u la s p a ra g a se s se a p lic a n en fo rm a e stric t a a p r e sio n e s lo b a st a n te b a ja s p a ra q u e la e c u a c ió n d e e sta d o d e los g a se s id e a le s se a v á lid a.

Rango
P e so U n id a d (u n id a d e s
C o m p u e s to F ó rm u la m o le c u la r E sta d o F o rm a d e te m p . a X 103 /> X |()5 c X 10x d X I 0 12 d e T)

A c e tile n o c 2h 2 2 6 .0 4 8 ' °C 4 2.4 3 6 .0 5 3 - 5 .0 3 3 18.20 0 -1 2 0 0

A c e to n a c h 3c o c h 3 5 8 .0 8 1 1 °C 123.0 18.6 - 3 0 -6 0

g 1 °C 7 1 .9 6 2 0 .1 0 - 1 2 .7 8 3 4 .7 6 0 -1 2 0 0
A c id o n ítric o n h o 3 6 3 .0 2 1 1 °C 110.0 25
A c id o su lfú ric o h 2s o 4 9 8 .0 8 1 1 °C 139.1 15.59 10-45
A gua I l 20 18.016 1 1 °C 7 5 .4 0 -1 0 0

g • °C 3 3 .4 6 0 .6 8 8 0 0 .7 6 0 4 - 3 .5 9 3 0 -1 5 0 0
A ire 2 9 .0 g I °C 2 8 .9 4 0 .4 1 4 7 0.319 1 -1 .9 6 5 0 -1 5 0 0

g • K 2 8 .0 9 0 .1 9 6 5 0 .4 7 9 9 -1 .9 6 5 2 7 3 -1 8 0 0
A lc o h o l e tílic o (e ta n o l) C 2H 5O H 4 6 .0 7 1 1 °C 103.1 0
1 1 °C 158.8 100

g 1 °C 6 1 .3 4 15.72 -8 .7 4 9 19.83 0 -1 2 0 0
A lc o h o l m e tílic o c h 3o h 3 2 .0 4 1 1 °C 75 .8 6 16.83 0 -6 5

Tablas de propiedades ñsicas

(m e ta n o l) g 1 °C 4 2 .9 3 8.301 -1 .8 7 - 8 .0 3 0 -7 0 0
A m o n ia c o n h 3 17.03 g 1 °C 35 .1 5 2 .9 5 4 0.4 421 - 6 .6 8 6 0 -1 2 0 0
A z u fre s 3 2.0 7 c 1 K 15.2 2 .68 2 7 3 -3 6 8
(R ó m b ic o )
c 1 K 18.3 1.84 3 6 8 -3 9 2
(M o n o c lín ic o )

639
(continúa)
 640
T a b la B .2 (C on tinu ac ió n.)

Rango

Apéndice B
Peso J n id a d (u n id a d e s
C o m p u e sto F ó rm u la m o le c u la r E sta d o F orr e tem p . a X 101 b X 105 c X 10x í/X 1012 d e T)

B encen o c 6h 6 78.11 1 1 °C 1 2 6 .5 2 3 .4 6 -6 7

g 1 °C 7 4 .0 6 3 2 .9 5 -2 5 .2 0 7 7 .5 7 0 -1 2 0 0

B ro m u ro d e h id ró g e n o HBr 8 0 .9 2 g 1 °C 2 9 .1 0 -0 .0 2 2 7 0 .9 8 8 7 -4 .8 5 8 0 -1 2 0 0

« -B u ta n o C 4 H 10 5 8 .1 2 g 1 °C 9 2 .3 0 2 7 .8 8 -1 5 .4 7 3 4 .9 4 0 -1 2 0 0

C a rb o n a to d e c a lc io C aC 03 100 .0 9 c 2 K 8 2 .3 4 4 .9 7 5 - 1 2 . 8 7 X 1o 10 - 2 7 3 -1 0 3 3

C a rb o n a to d e so d io N a 2C 0 3 105 .9 9 c 1 K 121 2 8 8 -3 7 1

C a rb o n a to d e so d io N a2C 03 2 8 6 .1 5 c 1 K 5 3 5 .6 298

d e c a h id ra t a d o • i o h 2o
C a rb o n o C 12.01 c 2 K 1 1 .1 8 1 .0 9 5 -4 .8 9 1 X 1 0 10 2 7 3 -1 3 7 3

C a rb u r o d e c a lc io CaC ’2 6 4 .1 0 c 2 K 6 8 .6 2 1 .1 9 - 8 . 6 6 X 1 0 '° - 2 9 8 -7 2 0

C ia n u ro d e h id ró g e n o HCN 2 7 .0 3 g 1 °C 3 5 .3 2 .9 0 8 1 .0 9 2 0 -1 2 0 0

C ic lo h e x a n o C 6H , 2 8 4 .1 6 g 1 °C 9 4 .1 4 0 4 9 .6 2 - 3 1 .9 0 8 0 .6 3 0 -1 2 0 0

C ic lo p e n ta n o C SH , 0 7 0 .13 g 1 °C 7 3 .3 9 3 9 .2 8 - 2 5 .5 4 6 8 .6 6 0 -1 2 0 0

C lo ro C12 70.91 g 1 °C 3 3 .6 0 1 .3 6 7 - 1 .6 0 7 6 .4 7 3 0 -1 2 0 0

C lo r u ro d e h id ró g e n o HC1 3 6 .4 7 g 1 °C 2 9 .1 3 -0 .1 3 4 1 0 .9 7 1 5 —4 .3 3 5 0 -1 2 0 0

C l o ru ro d e m a g n e sio M g C l2 9 5 .2 3 c 1 K 7 2 .4 1 .5 8 2 7 3 -9 9 1

C o b re Cu 6 3 .5 4 c 1 K 2 2 .7 6 0 .6 1 1 7 2 7 3 -1 3 5 7

C um eno C 9 H I2 1 20.19 g 1 °C 1 3 9 .2 5 3 .7 6 - 3 9 .7 9 1 2 0 .5 0 -1 2 0 0

( iso p ro p ilb e n c e n o )
D ió x id o d e a z u fre S02 6 4 .0 7 g 1 °C 3 8 .9 1 3 .9 0 4 -3 .1 0 4 8 .6 0 6 0 -1 5 0 0

D ió x id o d e c a r b o n o co2 44 .01 g 1 °C 3 6 .1 1 4 .2 3 3 -2 .8 8 7 7 .4 6 4 0 -1 5 0 0

D ió x id o d e n i tró g e n o n o 2 4 6.0 1 g 1 °C 3 6 .0 7 3 .9 7 -2 .8 8 7 .8 7 0 -1 2 0 0

E ta n o c 2h 6 3 0 .0 7 g 1 °C 4 9 .3 7 1 3 .9 2 -5 .8 1 6 7 .2 8 0 0 -1 2 0 0

E tile n o C 2H 4 2 8 .0 5 g 1 °C + 4 0 .7 5 1 1 .4 7 -6 .8 9 1 1 7 .6 6 0 -1 2 0 0

F o rm a ld e h íd o c h 2o 3 0 .0 3 g 1 °C 3 4 .2 8 4 .2 6 8 0 .0 0 0 0 - 8 .6 9 4 0 -1 2 0 0

H e lio He 4 .0 0 g 1 °C 2 0 .8 0 -1 2 0 0

n -H e x a n o C6H14 8 6 .1 7 1 1 °C 2 1 6 .3 2 0 -1 0 0

(continúa)
 g 1 °C 137 .4 4 4 0 .8 5 - 2 3 .9 2 5 7 .6 6 0 -1 2 0 0
H id ró g e n o H, 2 .0 1 6 g 1 °C 2 8 .8 4 0 .0 0 7 6 5 0 .3 2 8 8 - 0 .8 6 9 8 0 -1 5 0 0
H id ró x id o d e c a lc io C a (O H ) 2 7 4 .1 0 c 1 K 89.5 2 7 6 -3 7 3
Iso b u ta n o C 4H | o 5 8 .1 2 g I °C 8 9 .4 6 3 0.1 3 -1 8 .9 1 4 9 .8 7 0 -1 2 0 0
Iso b u te n o c 4h s 5 6 .1 0 g I °C 8 2.8 8 2 5 .6 4 - 1 7 .2 7 5 0 .5 0 0 -1 2 0 0
M e ta n o c h 4 16.04 g 1 °C 34 .31 5 .4 6 9 0 .36 6 1 - 1 1 .0 0 0 -1 2 0 0

g 1 K 19.87 5.021 1.268 - 1 1 .0 0 2 7 3 -1 5 0 0

M e tilc ic lo h e x a n o c 7h 14 9 8 .1 8 g 1 °C 121.3 5 6 .5 3 - 3 7 .7 2 100.8 0 -1 2 0 0
M e tilc ic lo p e n ta n o Q H ,2 8 4 .1 6 g 1 °C 9 8 .8 3 4 5 .8 5 7 -3 0 .4 4 83.81 0 -1 2 0 0
M o n ó x id o d e c a rb o n o CO 28.01 g 1 °C 2 8 .9 5 0 .4 1 1 0 0 .3 5 4 8 - 2 .2 2 0 0 -1 5 0 0
N itró g e n o n 2 2 8 .0 2 g 1 °C 2 9 .0 0 0 .2 1 9 9 0 .5 7 2 3 -2 .8 7 1 0 -1 5 0 0
O x id o d e c a lc io C aO 5 6 .0 8 c 2 K 4 1 .8 4 2 .0 3 - 4 . 5 2 X I 0 10 2 7 3 -1 1 7 3
Ó x id o d e m a g n e sio M gO 4 0 .3 2 c 2 K 4 5 .4 4 0 .5 0 0 8 - 8 .7 3 2 X 10 0 2 7 3 -2 0 7 3
O x id o fé rric o Fe2O j 15 9.7 0 c 2 K 1 03.4 6.711 - 1 7 . 7 2 X 1 0 10 - 2 7 3 -1 0 9 7
O x id o n ítric o NO 30.01 g 1 °C 2 9 .5 0 0 .8 1 8 8 - 0 .2 9 2 5 0 .3 6 5 2 0 -3 5 0 0
O x id o n itro so N 20 4 4 .0 2 g 1 °C 3 7 .6 6 4.151 - 2 .6 9 4 10.57 0 -1 2 0 0
O x íg e n o 0 2 3 2 .0 0 g 1 °C 2 9 .1 0 1.158 -0 .6 0 7 6 1.311 0 -1 5 0 0
n -P e n ta n o C 5H 12 7 2.15 1 1 °C 155.4 4 3 .6 8 0 -3 6

g 1 °C 114.8 3 4 .0 9 - 1 8 .9 9 4 2 .2 6 0 -1 2 0 0
P ro p a n o c 3h 8 4 4 .0 9 g 1 °C 6 8 .0 3 2 2 2 .5 9 - 1 3 .1 1 31.71 0 -1 2 0 0
P ro p ile n o c 3h 6 4 2 .0 8 g 1 °C 5 9 .5 8 0 17.71 - 1 0 .1 7 2 4 .6 0 0 -1 2 0 0
T etra c lo ru ro d e c a rb o n o C C I4 15 3.8 4 1 1 K. 9 3 .3 9 12.98 2 7 3 -3 4 3
T ctró x id o d e n itró g e n o n 2o 4 9 2 .0 2 g 1 °C 7 5 .7 12.5 - 1 1 .3 0 -3 0 0

Tablas de propiedades físicas

T o lu e n o c 7h 8 9 2 .1 3 1 1 °C 148.8 3 2 .4 0 -1 1 0

g 1 °C 9 4 .1 8 3 8 .0 0 - 2 7 .8 6 8 0 .33 0 -1 2 0 0
T rió x id o d e a z u fre so3 8 0 .0 7 g 1 °C 4 8 .5 0 9 .1 8 8 - 8 .5 4 0 3 2 .4 0 0 -1 0 0 0
S u lfa to d e a m o n io (N H 4)2S 0 4 132.15 c 1 K 2 1 5 .9 2 7 5 -3 2 8
S u lfu r o d e h id r ó g e n o h 2s 3 4 .0 8 g 1 °C 33.51 1.547 0 .3 0 1 2 -3 .2 9 2 0 -1 5 0 0

" A d a p ta d o e n p a r te d e D. M . H im m e lb la u , Basic P rincipies and Calculations in Chem ical Engineering, 3 a . e d ic ió n , © 1 97 4, ta b la E .l . A d a p ta d o c o n a u to riz a c ió n

d e P rc n tic e -H a ll, In c ., E n g le w o o d C liffs, NJ.

641