11.25.
- para el sistema etileno (1) propileno (2)
como gas calcule, calcule f1,f2,01,02 a T=150 C
P=30bar
T= 423
ij Tcij/k Pcij/bar Vcij/cm^3 Zcij
11 etileno 282.3 50.4 131 0.281
22 propileno 365.6 46.65 188.4 0.289
12 mezcla 323.95 48.52 159.7 0.285
Tr11=T/Tc 1.49840595
Tr22= 1.15700219
Tr12= 1.30575706
B^0= (0.083)-0.422/(Tr)^1.6 -0.13795573
B^022= -0.25117793
B^012= -0.19238015
0.139
B^1=0.139-(0.172)/(Tr)^4.2 0.10753088 0.172
B^1 22= 0.04577661
B^1 12 0.08290729
B11=B^0+wij *B^1 -0.12860054
B22= -0.2447692
B12= -0.18301163
wij
0.087
0.14
0.113
83.14
B11=(Bij * R * Tcij)/Pcij -59.8870837
B22= -159.485547
B12= -101.588817
&12=2B12-B22 16.1949975
300
ln01=P/R*T (B11+Y2^2*&12) -0.00452494
ln022= -0.01343557
0.99548528 0.98665429
A B
11.5.- para H2O auna temperatura de 300 C y para presion
(100 bar) calcule los valores de fi y 0i a apartir de los datos
tablas de vapor.
𝐺_𝑖=𝑇_𝑖 (𝑇)+𝑅∗𝑇∗𝑙𝑛∗𝑓_𝑖 𝐺_𝑖^∗=𝑇_𝑖 (𝑇)+𝑅∗𝑇
𝑙𝑛 𝑓_𝑖/(𝑓_𝑖^∗ 𝑙𝑛 𝑓_𝑖/(𝑓_𝑖^∗ )=1/𝑅
)=1/(𝑅∗𝑇) [(𝐻_𝑖−𝐻_𝑖^∗)/𝑇−(𝑆_𝑖−𝑆
(𝐺_𝑖−𝐺_𝑖^∗)
𝐻_𝑖^∗=3076.8 𝐽/𝑔 3076.8 𝑆_𝑖^∗=10.3450 𝐽/(𝑔
𝐻_𝑖=2962 𝐽/𝑔 𝑆_𝑖=6.3642
2962
𝐽/(𝑔∗𝐾)
𝑙𝑛
8.19169697
𝑓_𝑖/𝑓^𝑖
=
e^8.1916= 3610.84456
𝑓_𝑖=(3611)(𝐹_𝐼^∗ ) ∴ 𝑓_𝑖=("3610.84456 " )(1𝐾𝑃𝑎)="3610.84
∅_𝑖^𝑠𝑎𝑡=0.78 𝑓_𝑖^𝑠𝑎𝑡=6738.9
43 𝐾𝑃𝑎
𝑉_𝑖^𝑙 25.275045
=
𝑓_𝑖=∅_𝑖^𝑠𝑎𝑡∗𝑃_𝑖^𝑠𝑎𝑡 ∗𝑒𝑥
(𝑃−𝑃_𝑖^𝑠𝑎𝑡 ))/𝑅𝑇=
∅_𝑖=𝑓_𝑖/
𝑃= 0.67897479
300 C y para presiones hasta 10000 KPa
a apartir de los datos de la informacion de las
𝐺_𝑖^∗=𝑇_𝑖 (𝑇)+𝑅∗𝑇∗𝑙𝑛∗𝑓_𝑖^∗
R 8.314
𝑓_𝑖/(𝑓_𝑖^∗ )=1/𝑅
𝐻_𝑖−𝐻_𝑖^∗)/𝑇−(𝑆_𝑖−𝑆_𝑖^∗)] PMH2O 18.015
𝑆_𝑖^∗=10.3450 𝐽/(𝑔 ∗𝐾)
= 10.345 P 4000
𝑆_𝑖=6.3642
= 6.3642
𝐽/(𝑔∗𝐾)
𝑓_𝑖/
(𝑓_𝑖^∗ )=3610.8
4456
56 " )(1𝐾𝑃𝑎)="3610.84456 " ∅_𝑖=𝑓_𝑖/𝑃=
0.90271114
^𝑠𝑎𝑡=6738.9
𝑎 𝑃_𝑖^𝑠𝑎𝑡=8592. 8592.7
7
=∅_𝑖^𝑠𝑎𝑡∗𝑃_𝑖^𝑠𝑎𝑡 ∗𝑒𝑥𝑝 (𝑉_𝑖^𝑙
𝑃_𝑖^𝑠𝑎𝑡 ))/𝑅𝑇= 6789.74794719
determinar los coeficiente de fugacidad que se conocen por
(11.63) para el nitrogeno y el metano en una mezcla de N2
(2) a 200 K y 30 bar si la mezcla contiene 40%mol de N2
B11= -35.2 B22= -105
𝛿_12=2∗𝐵_12−𝐵_11−𝐵_22 20.6
=
𝑙𝑛∅_1=𝑃/𝑅𝑇
(𝐵_11+𝑦_2^2∗𝛿_12 )= -0.0501275
𝑙𝑛∅_2=𝑃/𝑅𝑇
(𝐵_22+𝑦_1^2∗𝛿_12 )= -0.1834929
d que se conocen por la ec.
n una mezcla de N2 (1) CH4
ene 40%mol de N2
B12= -59.8 P= 30
T= 200
∅_1= 0.95110815
∅_2= 0.83235778
de la ec. (11.67) calcular un valor para la fugacidad
del vapor de 1-butano a 200 Cy 70 bar
Tr Pr w p
1.127 1.731 0.191 70
interpolando en calculadora
me queda
∅^0=0.6172 ∅^1=1.0893
∅=(∅^0) 0.62736616
(∅^1 )^𝑤=
𝑓=(∅)(𝑃)= 43.9156313
fugacidad
estime 01 y 02 mediante las ec (11.63) para una
mezcla equimolar de metil etil cetona (1) toluneno (2)
a 50 C y 25 KPa
T P
323 0.25
ij Tcij/K Pcij/bar Vcij/cm^3 Zcij wij
A 11 535.5 41.5 267 0.249 0.323
B 22 591.8 41.1 316 0.264 0.262
C 12 563.65 41.3 291.5 0.2565 0.2925
𝑇_𝑟=𝑇/
0.6031746 A
𝑇𝑐=
0.5457925 B
0.57305065 C
0.083
𝐵^0=0.083−0.422/
(𝑇𝑟^1.6 )= -0.86455314 A
-1.02890671 B
-0.94549843 C
0.139
𝐵^1=0.139−0.172/(𝑇𝑟^4.2 )=
-1.29869793 A
-2.04882554 B
-1.6438623 C
𝐵_𝑖𝑗=𝐵^0+𝑊∗𝐵^1=
𝐵_𝑖𝑗=𝐵^0+𝑊∗𝐵^1= -1.28403257 A
-1.56569901 B
-1.42632815 C
R=
〖𝐵∗〗 _𝑖𝑗=(𝐵_𝑖𝑗∗𝑅∗𝑇 -1377.5185 A
𝑐𝑖𝑗)/𝑃𝑐𝑖𝑗=
-1874.35321 B
-1618.41142 C
𝛿_12= 〖 2(𝐵 〗 _12)−𝐵_11−𝐵 15.0488735
_22=
𝑙𝑛∅_1=𝑃/
𝑅𝑇(𝐵_11+𝑦_2^2∗𝛿_12)= -0.01278902
𝑙𝑛∅_2=𝑃/𝑅𝑇(𝐵_22+𝑦_1^2∗𝛿_12)=
-0.01741431
∅_1= 0.98729242
∅_2= 0.98273644
ara una
toluneno (2)
0.422
0.172
83.14
calcule 0 y f mediante R/K para una de los sig. casos dioxido
carbono
T W Tc Pc R P
350 0.224 304.2 73.83 8.134 35
Tr=T/Tc= 1.15055884
Pr=P/Pc= 0.47406203 𝑧=1+𝛽−𝑞∗𝛽 (𝑧−
𝐵=Ω 𝑃𝑟/𝑇𝑟= 𝑧=1+"0.03569807 −(0
0.03569807
" )/(𝑧(𝑧+"0.03569807 "
𝑞=(Ψ∗𝛼(𝑇𝑟)" " )/(𝛺∗𝑇𝑟) Ζ=1".03569807"−
3.99792005
(Ζ−1."03569807" )(Ζ^2
Ζ)=−0.1423Ζ+ 〖 5.065
Ζ^3+ "0." 0356Ζ^2−1
Ζ+ 〖 5.0658×10 〗 ^(−
𝐵^0=0.083−0.422/(𝑇𝑟^1.6 )=
𝐵^1=0.139−0.172/(𝑇𝑟^4.2 )=
𝐵_𝑖𝑗=𝐵^0+𝑊∗𝐵^1 (𝑅∗𝑇𝑐)/𝑃𝑐=
𝑙𝑛∅=(𝐵∗𝑃)/
𝑅𝑇=
∅= 0.90218477
𝑉=(𝑍∗𝑅∗𝑇)/𝑃=
f=∅*P= 31.5764671
os sig. casos dioxido de
𝜎 ∈ Ψ Ω a(Tr)
1 0 0.42748 0.08664 -0.5
𝑧=1+𝛽−𝑞∗𝛽 (𝑧−𝛽)/((𝑧+∈𝛽)(𝑧+𝜎" " β" )" )
=1+"0.03569807 −(0.03569807 )(3.99792005 )" (𝑧−"0.03569807
/(𝑧(𝑧+"0.03569807 " )) " "
Ζ=1".03569807"−(0.1423(Ζ−"0.03569807" ))/(Ζ^2+"0.03569807" Ζ)
Ζ−1."03569807" )(Ζ^2+"0.03569807 "
)=−0.1423Ζ+ 〖 5.0658×10 〗 ^(−3)
Ζ^3+ "0." 0356Ζ^2−1.0356 〖 Ζ 〗 ^2−0.0356 Ζ=−0. 1423
Ζ+ 〖 5.0658×10 〗 ^(−3)
Ζ^3−Ζ^2+0. 1055 Ζ− 〖 5.0658×10 〗 ^(−3)=0
Z= 0.8875
83−0.422/(𝑇𝑟^1.6 )=
-0.25417729
39−0.172/(𝑇𝑟^4.2 )=
0.04356419
∗𝑇𝑐)/𝑃𝑐=
-8.37280862
∅=(𝐵∗𝑃)/
𝑇= -0.10293593
72.18925
3569807
0.03569807" Ζ)
