CH4 + 1.5a (O2 + 3.76 N2) x CO2 + y H2O + 3.76a*1.
5 N2 + w O2
C: 1=x w = 0.5a
H: 4 = 2y y=2
O: 2*1.5a = 2x + y + 2w a=2
CH4 + 3 (O2 + 3.76 N2) CO2 + 2 H2O + 11.28 N2 + O2
a)
Reactivos hf (KJ/Kmol) h 298 K Entalp. TP # Moles
CH4 -74850 1 -74850
O2 0 8682 8682 3 0
N2 0 8669 8669 11.28 0
hreact = -74850
Productos
CO2 -393520 9364 h CO2 1 -402884
H2O -241820 9904 h H2O 2 -503448
O2 0 8682 h O2 1 -8682
N2 0 8669 h N2 11.28 -97786.32
15.28
hprod = -1012800.32
}
Entalpia de combustion:
hC = Hp-hR
937950.32 KJ
h CO2 + 2h H2O + 11.28h N2 + h O2 =
Por tanteo:
61384.1832
1340 CO2
1580 H2O
1860 O2
1940 N2
PraT=1900 K
CO2 94793 94793
H2O 77517 155034
O2 64116 64116
N2 61220 690561.6
1004504.6
praT=1800K
CO2 88806 88806
H2O 72513 145026
O2 60371 60371
N2 57651 650303.28
944506.28
Interpolando
1900 1004504.6
T 937950.32
1800 944506.28
T= 1789.073
b)
n(#moles) [Link](Y) Entropia Ruln(yiPm) n*SI
CH4 1 1 186.16 186.16
O2 3 0.21 205.03 -12.97522538 654.0157
N2 11.28 0.79 191.5 -1.959795481 2182.2265
Sreac = 3022.4022
Entro.1789K
CO2 1 0.065 302.547 -22.668 325.215
H2O 2 0.131 258.957 -16.906 551.726
O2 1 0.065 264.471 -22.668 287.140
N2 11.28 0.738 247.977 -2.523 2825.641
15.28 Sprod = 3989.7216
Sgen = Spro - Sreac = 967.3194 KJ/Kmol*K
Exergia destruida =
Xdest = To * Sgen = 288261.18035
Wrev = 288.261 MJ/KmolCH4
CO2 H2O O2
302.271 1780 258.708 1780 264.283
s 1789 S 1789 S
302.884 1800 259.262 1800 264.701
302.54685 258.9573
N2
1780 247.798 1780
1789 S 1789
1800 248.195 1800
264.4711 247.97665