Una mezcla metano(1), etano(2), propano(3) a 100℃ P=35 bar y 1=0.21 y 2=0.43 y 3=0.
36
Determine:
1. Fugacidad en componente 1,2 y 3
2. Coeficiente de fugacidad en componente 1,2 y 3
a) Como gas
b) Suponiendo que
ij Tcij Pcij Vcij zcij wij Trij B° B’ Bij
K bar
11 190.56 45.99 0.0902 0.288 0.012 1.95 -0.13 0.128 -0.128
22 305.32 48.72 0.1479 0.284 0.100 1.22 -0.29 0.064 -0.283
33 396.83 42.48 0.2029 0.280 0.152 1.00 -0.41 -0.033 -0.415
12 241.20 49.18 0.1166 0.286 0.056 1.54 -0.20 0.110 -0.193
13 265.47 45.09 0.1390 0.284 0.082 1.40 -0.23 0.097 -0.222
23 336.03 45.30 0.1739 0.282 0.126 1.11 -0.34 0.028 -0.336
a)
T=100℃ = 373.15K
δ12=0.44
δ13=0.382
δ23=0.154
Componente 12
1
Tcij=( Tci Tc j ) 2 (1−K i j)
Tcij=(190.56 ( 305.32 ))1 /2=241.20 K
zci j R Tci j
Pcij=
Vci j
0.286(0.08314)( 241.20)
Pcij= =49.18 bar
0.1166
T
Trij=
Tci j
373.15
Trij= =1.54
241.20
ln ∅1=−0.052 ∅ 1=0.949
Componente 13
Tcij=(190.56 ( 396.83 ) )1 /2 =265.47 K
0.284 (0.08314)(265.47)
Pcij= =45 .09 bar
0. 1390
373.15
Trij= =1. 40
265.47
ln ∅2=−0.296 ∅ 1=0. 743
Componente 23
Tcij=(305.32 ( 396.83 ))1 /2=336.03 K
0.282( 0.08314)(337.03)
Pcij= =45.30 bar
0.1739
373.15
Trij= =1.11
336.03
ln ∅3=−0. 449 ∅ 3=0.638
ƒ^1=33.21 ¯¿
ƒ^2=26.00 ¯¿
ƒ^3=22.33 ¯¿
b) Suponiendo
l n ∅ 1=−0. 144 ∅ 1=0. 8658
ln ∅2=−0.319 ∅ 1=0. 7268
ln ∅3=−0. 468 ∅ 3=0.6262