picolinoylとは 意味・読み方・使い方

An asymmetric ketone compound such as acetophenone, etc., is reduced with trichlorosilane in the presence of an optically active N-picolinoylpyrrolidine derivative represented by formula (1) (R is a 2-5C alkoxycarbonyl group, a 2-5C alkoxymethyl group or a hydroxymethyl group) such as picolinoyl-(S)-2-methoxycarbonylpyrrolidine.例文帳に追加

たとえばＮ−ピコリノイル−（Ｓ）−２−メトキシカルボニルピロリジンのような下記式（Ｉ）で示される光学活性Ｎ−ピコノイルピロリジン誘導体の存在下に、アセトフェノン等の非対称ケトン化合物をトリクロロシランで還元する。 - 特許庁