oxazoliniumとは 意味・読み方・使い方

名詞

oxazolinium ‎(複数形 oxazoliniums)

1. (有機化学) Any cation derived from an oxazole
   • 2016 February 13, “Probing the Catalytic Mechanism of Vibrio harveyi GH20 ?-N -Acetylglucosaminidase by Chemical Rescue”, in PLOS ONE^[1], DOI:10.1371/journal.pone.0149228:

     GH3 GlcNAcases catalyse the hydrolytic reaction through a standard ‘retaining’ mechanism involving a covalent glycosyl-enzyme intermediate [14 ,15 ], while GH20 and GH84 GlcNAcases hydrolyse chitooligosaccharides through a ‘substrate-assisted’ mechanism involving the transient formation of an oxazolinium ion intermediate [16 –18 ].